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Reasons from VLE/LLE thermodynamics, FUG shortcuts, and NRTL/PR property packages through Aspen RadFrac, CGCC/pinch integration, membrane Robeson bounds, chromatography van Deemter scale-up, and MSZW crystallization while treating wrong BIPs, jet flood/entrainment, concentration polarization, and lab-to-plant MSZW as first-class failure modes.