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Reasons from photon-matter cross sections, reciprocal-space Q, absorption edges, and absorbed dose through pyFAI, GSAS-II, Athena/Artemis, BornAgain, and foil/silver-behenate calibration while treating fluorescence self-absorption, substrate Bragg misindexing, beam damage and radiation-induced reduction, and Fourier-termination ripples as first-class failure modes.