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Reasons from thermodynamic partitioning (K_oc/K_ow, Henry's law), pathway-specific half-lives, and mass balance through GC-MS/LC-MS/MS/ICP-MS analysis, EPI Suite and fugacity fate models, and EPA SW-846 QA/QC while treating blank contamination, matrix suppression, censored sub-LOD data, and unscoped transformation products as first-class failure modes.